This is a starting point for material selection, not an answer. The answer comes from the ASME B16.34 rating table for the specific grade at your design temperature, and from your project specification. What this page gives you is the shape of the decision.

Body materials by temperature

GradeSpecificationPractical upper limitTypical use
A105 / A105NASTM A105~425 °CFeedwater, condensate, auxiliary steam, general forged small bore
WCBASTM A216~425 °CCast equivalent of A105 for larger bores
F11 (1.25Cr-0.5Mo)ASTM A182~510 °CModerate-temperature steam, feedwater heaters
WC6ASTM A217~510 °CCast equivalent of F11
F22 (2.25Cr-1Mo)ASTM A182~540 °CReheat steam, high-temperature feedwater, older main steam
WC9ASTM A217~540 °CCast equivalent of F22
WB36 (15NiCuMoNb5)EN / DIN~400 °CEuropean feedwater system designs - not an F22 substitute
F91 (9Cr-1Mo-V)ASTM A182~600 °CSupercritical main steam and hot reheat
C12AASTM A217~600 °CCast equivalent of F91
F92 (9Cr-2W)ASTM A182Above F91Ultra-supercritical, or where wall thickness must be reduced
F304 / F316ASTM A182~550 °C, corrosion-drivenAuxiliary, chemical, and corrosive service - not selected for creep
F347HASTM A182~650 °CAustenitic option where the piping is austenitic

Read “practical upper limit” carefully. These are indicative points beyond which the allowable stress falls to the extent that the required wall thickness becomes unreasonable. They are not code limits. The code limit for your case comes from the rating table for the class and grade you are actually buying.

Trim materials

MaterialTypical applicationNotes
13Cr / F6aGeneral seat and stem materialStandard trim for most power valves
F6NM (13Cr-4Ni)Higher-strength stem, creep-grade valvesBetter toughness than F6a
422SSHigh-temperature stemRetains strength above the F6a range
Stellite 6 overlaySeat and closure member facesCobalt-based, resists galling and erosion; standard for steam service
Stellite 21Where lower hardness with better toughness is wantedLess common
Inconel 718Hinge pins, springs, high-temperature fastenersWhere 13Cr will not do
Tungsten carbide overlayAbrasive serviceCoal chemical, ash-bearing streams; not standard for steam

Note that trim is a combination, not a single material. A trim specification names the seat, the closure member facing, the stem and the back seat. API 600 numbers some standard combinations; outside that scheme they have to be stated individually.

By system

SystemTypical conditionBodyTrimValve type
Main steam, USC25-31 MPa, 566-610 °CF91, F92F6NM/422SS + Stellite 6Pressure seal gate; globe for drains
Main steam, subcritical17 MPa, 540 °CF22, F91F6a + Stellite 6Pressure seal gate
Hot reheatLower pressure, 540-620 °CF91, F92F6NM + Stellite 6Pressure seal gate
Cold reheatModerate bothF11, F22F6a + Stellite 6Gate or check
HP feedwaterAbove drum pressure, 150-300 °CA105N, F11, F22, WB36F6a + Stellite 6Pressure seal gate, check
Extraction steam0.05-5 MPa, 150-450 °CA105, WCB, F11F6a + Stellite 6Swing check, powered
Boiler drains / blowdownDrum pressure, flashingA105N, F11, F22F6a + Stellite 6Globe, hardfaced
Auxiliary / gland steamLow bothA105, WCBF6aGate, globe, check

Three things this table cannot tell you

Whether your specification permits the grade. Client specifications often restrict the acceptable list, sometimes to a single grade per system. That governs.

Whether the material is obtainable in your section and on your schedule. Availability of large F92 forgings is a real constraint, and a metallurgically optimal choice that cannot be delivered is not a choice.

Whether the weld is qualified. Matching a valve body grade to the pipe grade matters because the site weld has to be qualified for that combination and heat treated accordingly. A body grade that creates a dissimilar-metal weld at the site interface has consequences the valve datasheet does not show.

How to use this in an enquiry

Send the design pressure, design temperature, medium and - if you have it - the piping class extract for the line. We will state the grade we propose, the rating it gives at your condition, and any point where we would rather propose something different from what the specification names. That last category is the useful part of a technical response.